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Combine flour, 1/2 cup plus 2 tablespoons cocoa, 1/2 cup sugar, baking powder, and salt in a 1 1/2 quart shallow microwave safe dish. Add egg yolks, butter, vanilla, chocolate chips, and water to the mix, and stir until almost combined (batter will be lumpy). Stir remaining 2 tablespoons cocoa and remaining 1/4 cup sugar in a small bowl and sprinkle over batter. Microwave on high power until puffed, bubbling, and set (but still slightly jiggles), 4 to 5 minutes. Carefully remove from microwave and serve warm (see note).