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Step 1
Fill a wide, deep skillet or Dutch Oven with 1-inch of water. Bring to a boil over medium-high heat.
Step 2
Meanwhile, gently roll out the biscuits into 4.5-inch rounds. For each bun, spoon about 1 tablespoon of pulled pork onto the center of each dough round. Bring the edges of the biscuit together to the center. Pinch tops of the buns together to seal.
Step 3
Spray the bamboo steamer with cooking spray and line with parchment paper. (Cut slits in parchment paper to allow steam to escape if you don't have the precut liners.)
Step 4
Set the steamer basket over the boiling water. Add the biscuits to the basket, spacing evenly. Cover and steam for 15 minutes, until cooked through and puffed.
Step 5
Gently transfer the buns to a wire rack to cool slightly.