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Step 1
Preheat the oven to 350 degrees F (175 degrees C). Butter the bottom and sides of a 9x13-inch dish.
Step 2
Bring a pot of water to a boil. Add chicken and continue to boil until no longer pink, 5 to 10 minutes.
Step 3
Meanwhile, combine broccoli, cream of chicken soup, Cheddar cheese, 1/2 cup Parmesan cheese, mozzarella cheese, sour cream, and pepper in a large bowl. Mix well.
Step 4
Drain chicken and add to broccoli mixture. Mix well. Pour into the prepared baking dish and spread evenly.
Step 5
Bake in the preheated oven for 20 minutes. Add remaining Parmesan cheese on top and continue to bake until cheese is melted, 3 to 5 minutes.