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Lightly spray the bottom and sides of slow cooker with nonstick spray, if desired. Place chicken breasts on bottom of slow cooker.
Combine soy sauce, vinegar, honey, brown sugar, and garlic in a small bowl or measuring cup. Pour over chicken breasts.
Cook on High setting for 3-4 hours or 6-8 hours on Low setting, until chicken breasts are tender.
Remove chicken from slow cooker and shred with forks. Set aside.
Pour sauce into small saucepan. Combine cornstarch with water, and add to sauce. Over medium heat, bring sauce to a low boil, stirring often, and cook another minute, until sauce is thickened. Pour thickened sauce over shredded chicken.
Serve over rice or quinoa, topped with sesame seeds and sliced green onions. Enjoy!