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Place the edible glitter in a shallow bowl or plate that the top of your drink will fit into.
Use a pastry brush or your finger to apply the corn syrup along the edge of the glass and then dip the glass into the edible glitter to make a pretty rim.
Pour the stout into your glass and when ready to serve, top with the champagne. (If using chocolate liqueur with regular stout, layer the liqueur first then the stout.)