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Heat oven to 350°F (177°C). Lightly butter a 10-ounce ramekin with ¼ tablespoon butter. Set aside.
Place 2 tablespoons of butter in a small microwave safe bowl. Heat in microwave until just melted. Set aside.
Whisk together the sugar, flour, and cocoa powder in a small bowl until thoroughly combined.
Add the melted butter, egg yolk, and vanilla. Stir with a spoon or a rubber spatula to combine. Do not overmix.
Fold in the chocolate chips.
Pour the batter into the prepared ramekin. Spread into an even layer. Bake for 30 minutes.
Remove from the oven and let cool for 5 minutes before enjoying. Top with ice cream, if desired.