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Preheat oven to 400F.
Melt the butter in a microwave for about 30 seconds. Add the garlic, chives, black peppper, salt and 1 tablespoon of Parmesan cheese into the heated and melted butter, stir to mix well.
Toss the potatoes with the garlic chive butter. Stir to coat well and transfer them to an oven safe baking dish or skillet (cast-iron preferred). Cover the potatoes with aluminum foil and roast for 30 minutes.
Remove from heat, toss the potatoes well with the garlic chive butter at the bottom of the baking dish or skillet. Sprinkle the remaining 1 tablespoon of Parmesan cheese evenly on top of the potatoes and serve immediately.