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Step 1
In a large resealable plastic bag, add chicken and ¼ cup cornstarch. Season with salt and pepper and shake to coat.
Step 2
In a large pot over medium-high heat, add 2 tablespoons oil. Shake off excess cornstarch and add chicken to oil. Cook, in batches, until golden, about 7 minutes. Drain on a paper towel-lined plate.
Step 3
Add remaining 1 tablespoon oil to skillet. Add garlic and red pepper flakes cook until fragrant, 30 seconds. Add chicken broth, making sure to scrape up any brown bits with a wooden spoon.
Step 4
In a medium bowl, whisk hoisin sauce, honey, soy sauce, and lime juice with remaining 1 tablespoon cornstarch until combined. Add to skillet and simmer until slightly thickened, 1 minute.
Step 5
To sauce, add broccoli and cook until tender, 5 minutes. Return chicken to skillet and stir to coat. Simmer for 1 more minute.
Step 6
Garnish with sesame seeds and serve over rice.