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Step 1
Preheat oven to 425F degrees. Place a cast iron skillet or heavy duty oven safe skillet over medium high heat.
Step 2
In a small bowl, mash goat cheese with a fork until smooth. Stir in pepperoncini and thyme and season with salt and pepper.
Step 3
Use a paring knife to cut a slit in the thick side of each chicken breast. Create a pocket carefully using your fingers or the knife making sure to not cut through the back of the breast. Stuff each pocket with about 2 tablespoons of the goat cheese mixture.
Step 4
Divide goat cheese mixture evenly between each of the chicken breasts and press into the pockets. Pat the chicken dry on all sides and season with salt and pepper.
Step 5
Place chicken breasts skin side down in the heated skillet and cook for about 5 minutes. Carefully transfer the hot skillet to the preheated oven and bake until chicken is cooked through, about 18 to 20 minutes. Use a meat thermometer to check for doneness.
Step 6
Remove the skillet from the oven and carefully, using tongs, flip the chicken breasts over in skillet and let rest for 3 minutes before serving.
Step 7
Garnish with fresh thyme if desired.