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Step 1
Turn a burner to the highest setting and set your pepper directly on the flame. Use a pair of tongs to turn the pepper occasionally until the skin is completely blackened, about 8 minutes.
Step 2
Heat a gas grill to high or prepare a charcoal grill for direct heat. Place the peppers directly over the heat.
Step 3
Turn the peppers every 2 to 3 minutes until they are completely charred, about 10 minutes total.
Step 4
Position an oven rack as close as you can to the broiling element in your oven, and turn the broiler on to high.
Step 5
Place your peppers on a baking sheet and place it directly under the broiler.
Step 6
Use a pair of tongs to turn the peppers occasionally until the skin is completely blackened, about 8 minutes total.
Step 7
Put the still-warm pepper(s) in a heatproof bowl and cover either with plastic wrap, aluminum foil, or a pot lid.
Step 8
The skin will loosen as the pepper steams, and once it's cooled down a bit, you can easily remove the skin with your fingers.