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Add Water & Steamer Basket: Add 1 cup (250ml) cold water and (optional) 3 drops of liquid smoke in Instant Pot Pressure Cooker. Then, place a steamer basket in the pot.
Pressure Cook Chicken: Generously season both sides of chicken with salt and black pepper, then layer chicken on stainless steel steamer basket. Close lid and pressure cook at High Pressure for 8 minutes, then 10 minutes Natural Release.
Spice Up BBQ Sauce: If you are using store-bought BBQ sauce, add more depth of flavor with some garlic powder, onion powder, and white vinegar. For reference: we added ½ tsp garlic powder, ½ tsp onion powder, and ½ tbsp white vinegar to ⅓ cup Sweet Baby Ray's BBQ sauce. Please taste & adjust accordingly.
Apply BBQ Sauce to Chicken: Pat dry chicken and place them on an oven tray. Generously coat both sides of chicken with BBQ sauce.
Caramelize Instant Pot BBQ Chicken: Place BBQ Chicken under the broiler for 4 - 8 minutes until the BBQ chicken is browned & caramelized.