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Season the chicken, prep aromatics, and dice napa cabbage and slice shiitake. Set them aside ready to use.
In a 6-quart instant pot, press “Saute” and wait until the panel indicates hot, add 2 tbsp avocado oil and sear the chicken thighs about 3 minutes per side. Set the chicken aside.
Add 1 to 1.5 tbsp cooking oil, saute garlic, shallots, and ginger until fragrant (about 20-25 seconds). Season with a pinch of salt.
Deglaze the pot with 1 cup chicken stock and use a wooden spoon to scrape any brown bits. Press “Cancel”. Add chicken, shiitake, and cabbage stems on the top layer. Seal the lid and valve, Press “Manual” and adjust cook time to 15 minutes. Once the Instant Pot is done cooking (it will beep) wait for 10 minutes (natural release) before switching to quick release.
Stir-in cabbage leaves. Season the broth with coconut aminos and toasted sesame oil. Taste and see if you like to add the fish sauce or more salt. Garnish with chopped scallions and jalapeno, if using. Serve hot or warm with sautéed cauliflower rice, roasted sweet potatoes, or any rice or sweet potato noodles for a gluten-free meal.