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Step 1
Place barley in a large saucepan and cover generously with cold water. Add a generous pinch of salt and set over high heat. Bring to a simmer. Reduce heat to medium-low and simmer until the barley is tender, about 40 minutes. Drain through a fine mesh sieve.
Step 2
Whisk oil, lemon, garlic, salt and pepper in a large bowl.
Step 3
Add barley and stir to coat. Let the barley cool in the dressing mixture, stirring occasionally, about 30 minutes.
Step 4
Stir in bell pepper, tomatoes, olives and basil and stir to combine. Serve immediately or chill.