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Step 1
Place the chuck roast, au jus gravy mix, and ranch dressing mix into a slow cooker, making sure the chuck roast is coated in the gravy mix and dressing mix.
Step 2
Place the stick of butter on top of the chuck roast and place the pepperoncini peppers around the roast.
Step 3
Pour the water over everything.
Step 4
Cover the slow cooker and cook on low until the meat is fall-apart tender, about 8 hours.
Step 5
Transfer the meat and peppers to a cutting board and use two forks to shred the meat. Discard any fat.
Step 6
Strain the cooking liquid into a gravy separator or glass measuring cup.
Step 7
Skim the fat off the top and discard it.
Step 8
Pour the meat liquid into a small saucepan and cook it over medium-high heat on the stove-top.
Step 9
Slowly add the flour to the meat liquid as it cooks, whisking after each addition.
Step 10
Simmer the resulting gravy until it thickens, about 5 minutes.
Step 11
Return the meat and peppers to the slow cooker and pour the gravy over it.
Step 12
Serve hot over mashed potatoes.