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Step 1
Combine sugar and water in a small saucepan. Bring to a simmer over medium, stirring occasionally, until sugar dissolves, 2 to 3 minutes. Remove from heat, and let cool to room temperature, about 30 minutes.
Step 2
Transfer simple syrup to a blender. Add frozen peaches, corn syrup, and lemon zest and juice. Blend until smooth and creamy, about 1 minute. Transfer to a shallow container or an 8- x 4-inch loaf pan; cover and freeze until firm, about 4 hours. Let stand at room temperature about 10 minutes before serving. Sorbet may be stored in an airtight container in freezer up to 3 weeks.