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Preheat over to 375F
Sift flour and baking powder together then whisk to combine.
Cream butter, peanut butter and both sugars in a stand mixer fitted with a paddle attachment.
Mix in egg and vanilla extract then add flour mixture and beat until incorporated. You can chill dough for about 30 minutes if you're baking in advance but the dough can be rolled out and baked right away.
Roll dough into one inch balls. Roll each in sugar the place on baking sheet lined with parchment paper or a silicone sheet
Bake for about 7-8 minutes or until puffed and SLIGHTLY browned on the bottom. Remove from oven and press a chocolate kiss into the center of each cookie. Slight cracks are fine.
Bake cookies an additional 3 minutes.
Allow cookies to cool completely on baking sheet, enjoy warm.