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Step 1
Pour the melted chocolate in a small rimmed plate that fits your cup and the chopped peanuts in another.
Step 2
Turning the cup upside down, dip the rim into the chocolate, moving and twisting it around to make sure its well coated. Alternatively, use a clean paintbrush dedicated for kitchen use, to paint the chocolate around the rim of the cup.
Step 3
Dip the chocolate covered rim into the peanuts. If needed, gently press the peanuts with your fingers to adhere. Chill the cups in the fridge or freezer to set.
Step 4
Take a tablespoon or two of the milk, and whisk it with the cornstarch in a small bowl. Set aside.
Step 5
Place the remaining milk, cocoa powder, chocolates and peanut butter in a medium saucepan over medium heat.
Step 6
Heat the mixture, whisking constantly but gently, until the chocolate and peanut butter are completely melted and the mixture is steaming, about 5-8 minutes. Do not let it come to a boil. The mixture should be completely smooth and silky without little bits and dots of chocolate.
Step 7
Pour in the cornstarch mixture and whisk together. Continue to heat while constantly whisking until the mixture thickens slightly, about 1 minute.
Step 8
Place one scoop (or more if preferred) of vanilla ice cream in each cup, then pour the hot chocolate mixture over it. The ice cream will float up.
Step 9
Garnish with whipped cream, chocolate syrup and a peanut cup, if desired. Serve right away.