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Step 1
In a medium bowl, use a mixer to combine the peanut butter and 1/4 cup butter.
Step 2
Add the powdered sugar and vanilla, and continue mixing until combined and smooth.
Step 3
Use your hands to shape 1 tablespoon of the peanut butter mixture into a patty. Repeat with the remaining peanut butter mixture.
Step 4
Place the patties on a cookie sheet lined with waxed paper and refrigerate for about 30 minutes.
Step 5
Melt the chocolate in a double boiler, or in the microwave in 30-second increments.
Step 6
Add 2 tablespoons butter to the chocolate, and stir until the butter has melted and the mixture is smooth.
Step 7
Spoon about 2 teaspoons of chocolate into the bottom of a cupcake liner.
Step 8
Place a chilled peanut butter patty on top of the chocolate.
Step 9
Spoon just enough chocolate on top to cover the patty. Repeat with the remaining chocolate and peanut butter patties.
Step 10
Allow the peanut butter cups to set for a couple of hours before removing the cupcake liner.