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In small bowl, whisk together rice wine, soy sauce, toasted sesame oil, and brown sugar. In 6-quart slow cooker bowl, layer chicken, soy mixture, garlic, and ginger. Cover bowl with lid and cook until chicken is tender, 5 to 6 hours on Low. Transfer chicken to cutting board; shred and return to slow cooker bowl. Toss to coat in sauce. Serve chicken over rice with broccoli. Serve topped with scallions and chile.