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Position rack in middle of oven. Preheat oven to 250°F/121°C. Have a rimmed half-sheet pan handy.
Melt the butter and oil together in a large microwave safe bowl. Whisk in Worcestershire sauce, salt and cayenne, if using. Fold in cereal, nuts and pretzels until evenly coated. It will be a light coating. Scrape Chex Mix out onto rimmed sheet pan.
Bake for about 30 to 45 minutes or until lightly golden, turning once during baking. Cool pan on rack. Chex Mix is ready to eat or can be stored in an airtight container for up to 1 week at cool room temperature.