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Preheat oven to 400°F.
In a large bowl, toss mushrooms with oil, balsamic vinegar (if using), and pepper. Spread on a rimmed baking sheet in a single layer.
Bake for 10 minutes, toss with a spatula or spoon, and bake for 5-10 minutes more or until mushrooms are tender and golden brown. Sprinkle with salt and thyme, and serve warm or at room temperature.