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Once the brownie is made and cooled, begin the making the layers.
Beat together peanut butter, marshmallow cream, powdered sugar and vanilla. Mixture will be thick.
Gently spread the nougat on the brownies. Use your fingers or the back of a greased spatula.
Sprinkle with peanuts and gently press into the nougat. Refrigerate.
Add caramels and whipping cream to a sauce pan and heat over medium low heat, mixing constantly until caramels are melted.
Remove from heat and let stand to cool, about 15 minutes, stirring occasionally until warm to the touch.
Remove brownies from fridge and spread caramel on top of peanut layer. Return to the fridge for 10 minutes.
Heat chocolate in a microwave safe bowl for 60 seconds at 50% power and stir. Repeat and stir until smooth.
Pour onto caramel layer. Let stand to harden or refrigerate until hard.
Cut brownies into 24 squares before serving.