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Grease the sides and bottom of the crock pot with olive oil; sprinkle minced garlic over it.
Season chicken breasts with salt and pepper.
Add chicken to the crock pot and arrange it in one single layer.
In a small mixing bowl combine balsamic vinegar and brown sugar; whisk until thoroughly combined and pour it over chicken.
Top with sliced vegetables and Italian Seasoning.
Cover and cook on HIGH for 3 to 4 hours, or on LOW for 5 to 6 hours.
Remove cover and transfer chicken breasts to a cutting board; using two forks, shred the chicken.*
Stir the shredded chicken back into the crock pot.
Taste for seasonings and adjust accordingly.