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Step 1
Position rack about 8 inches from broiler; preheat to high. Line a baking sheet with foil.
Step 2
Place poblanos on the prepared pan. Broil, flipping once, until the skins are charred, 15 to 20 minutes. Transfer to a bowl and cover with plastic wrap. Let stand at room temperature for 10 to 15 minutes to help the skins loosen. Remove and discard the skins, stems and seeds.
Step 3
Meanwhile, whisk eggs, milk, shallot and salt in a large bowl.
Step 4
Preheat oven to 375°F. Arrange the poblanos in a 10-inch cast-iron skillet and pour the egg mixture on top. Top with cheese. Bake until the eggs are set, 20 to 25 minutes. Slice into 6 pieces and serve with toast.