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Step 1
Add potatoes, carrots, celery, onion, and thyme to the slow cooker.
Step 2
Cut beef into 1 ½-inch pieces, trimming off any excess fat or connective tissue. Combine with salt and pepper in a medium-sized bowl.
Step 3
Heat a large skillet over medium-high heat. Add the olive oil, once hot add the beef in a single layer.
Step 4
Cook until golden brown on one side, 2 minutes. Flip the pieces and cook the other side for 2 minutes. Transfer to the slow cooker.
Step 5
Reduce heat to medium and add garlic and saute for 30 seconds.
Step 6
Add balsamic vinegar to the pan with the beef drippings. Turn heat to medium-high, deglaze the pan using a whisk to scrape any browned bits and incorporate into the liquid.
Step 7
Reduce the sauce, stirring frequently, until 2 to 3 tablespoons of liquid remain, about 3 to 5 minutes. Transfer the pan liquid to the slow cooker.
Step 8
Add beef stock and soy sauce to the slow cooker. Cover and cook on "High" setting for 4 hours or "Low" setting for 8 hours.
Step 9
Whisk together cornstarch and water in a small bowl. Add cornstarch slurry to the slow cooker, stir to combine.
Step 10
Cook on "High" setting for 30 minutes to 1 hour, until the sauce becomes slightly thickened.
Step 11
Taste stew liquid and season with more salt and pepper as desired.
Step 12
Serve garnished with parsley.