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Whisk all of teriyaki sauce ingredients in a small bowl.
On medium heat in a cast-iron skillet brown chicken in oil until cooked on all sides and slightly crispy. *If pan isn't hot enough the chicken will steam so make sure pan is hot but not burning.*
Add teriyaki sauce to cooked chicken and stir for 1 to 2 minutes for sauce to thicken.
Stir in broccoli with chicken and sauce. Serve over rice with sprinkled sesame seeds and enjoy!