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Step 1
Combine smoked paprika, salt, pepper, onion powder, garlic, and cayenne in a small bowl.
Step 2
Pat chops dry with a paper towel and evenly distribute dry ingredient mixture on front and back of each chop. With fingertips, lightly rub dry ingredient mixture into the chops on both sides.
Step 3
Place chops on a plate and cover with plastic wrap. Refrigerate for at least 8 hours.
Step 4
Remove rubbed chops from the refrigerator and allow to come to room temperature, about 20 minutes.
Step 5
While chops are getting to room temperature, clean the grate of an outdoor gas grill and preheat to medium heat.
Step 6
When the grill is ready, lightly spray chops with avocado oil spray.
Step 7
Lightly oil the grill grates, place chops on the grill, and cook for about 3 minutes. Rotate chops 90 degrees to create a criss-cross grill pattern and continue grilling for 3 minutes. Turn chops and grill until pork chops are no longer pink inside, about 4 minutes more. An instant-read thermometer inserted into the center should read 145 degrees F (63 degrees C).
Step 8
Remove to a serving platter and allow to rest under a foil tent, for about 5 minutes. Serve warm.