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Step 1
Preheat the oven to 325 F. Place cast iron skillet on stovetop burner.
Step 2
Cut butter into 6 chunks and place in skillet with the chocolate. Cook over very low heat, stirring occasionally with a wooden spoon.TIP - Because the heat is low, it can take some time, so measure out your other ingredients while it's melting, so you aren't tempted to turn up the heat!
Step 3
When the chocolate and butter are completely melted, remove pan from the heat and add both sugars. Stir until everything is combined.
Step 4
Add eggs, one at a time, stirring well after each addition.
Step 5
Add vanilla and stir well.
Step 6
Add flour and salt and stir until there are no traces of flour left.
Step 7
Use a rubber spatula around the edge of the pan to clean off the sides and get all the batter into the middle.
Step 8
Place skillet in the oven and bake for 50 minutes. Insert a toothpick into the center to test for doneness. The toothpick should come out clean, with the possibility of a couple of crumbs. If it's still wet, put it back in the oven and bake at 5-minute intervals.
Step 9
Allow to cool on a wire rack for about 15 minutes. If you like warm brownies with ice cream and chocolate sauce, cut a wedge now. Otherwise, cool the brownies completely before cutting them into wedges.