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Whisk together orange juice, lime juice, olive oil, garlic, salt, chili powder, cumin, paprika, oregano, black pepper and cayenne pepper in a large bowl. Taste and adjust seasoning. Pour half of the dressing into a small container, and set aside for serving with the salad dressing.
Add chicken to the large bowl of dressing and set aside to marinate, for at least 15 minutes or up to overnight.
Heat a grill pan or large skillet over medium-high heat. Once hot, add chicken. Cook until chicken has reached an internal temperature of 165ºF, about 5-7 minutes per side. Remove chicken and loosely cover with foil to keep warm.
Add peppers and onion to the skillet and cook, stirring occasionally, until beginning to soften, about 5-7 minutes. Shut off heat, and let cool slightly.
Slice up chicken.
Assemble the salads: Divide lettuce, avocado, tomatoes, black beans (if using), cilantro leaves (if using) in a bowl. Divide the chicken and pepper mixture on top, then drizzle over 1-2 tablespoons of the reserved dressing. Serve immediately.