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Step 1
Wash the vegetables, then slice into thick wedges or triangles. If using asparagus, snap off woody bottoms, but do not slice.
Step 2
Whisk together the balsamic vinegar, olive oil, salt, garlic, and herbs in a small bowl until smooth.
Step 3
Set aside 3 tablespoons marinade. Add the remaining marinade along with the vegetables to one to two 1-gallon zip-top bags or a large baking dish.
Step 4
Toss to coat, then press as much air out of the bag (if using) as possible, or cover with plastic wrap (if using a baking dish). Allow to sit at room temperature for at least 15 minutes, or up to 3 hours.
Step 5
Prepare a grill or grill pan over medium high heat. Working in batches, grill the vegetables until tender and lightly charred all over, about 8-10 minutes for bell peppers, 7 minutes for yellow squash, zucchini, eggplant and mushroom, and 4 minutes for asparagus.
Step 6
Arrange on a platter, then drizzle with the reserved marinade. Serve warm or at room temperature.
Step 7
Preheat the oven to 425F.
Step 8
Place the vegetables on two baking sheets lined with parchment paper. Roast for 20 minutes, then flip and roast for another 10-25 minutes.
Step 9
Arrange vegetables on a platter, then drizzle with the reserved marinade. Serve warm or at room temperature.