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Step 1
In a large saucepan over medium heat, cook the water, brown sugar, salt, chile, if using, garlic, peppercorns, and thyme, stirring occasionally, until the salt and sugar dissolve. Remove from the heat and stir in the ice cubes.
Step 2
Once the brine is totally cool, transfer to a zip-top bag. Add the pork chops and turn to coat. Let brine in the refrigerator overnight (about 8 hours).
Step 3
Before cooking, pat the pork chops dry and let come to room temperature. Cook or grill as desired.