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Coat slow cooker with olive oil or spray with nonstick cooking spray. Spread 1/4 cup of BBQ sauce in the bottom of the slow cooker.
Arrange pork chops in a single layer in the slow cooker. Spread about 1/4 cup more BBQ sauce on top of pork chops. Repeat layers of pork chops and BBQ sauce, ending with BBQ sauce. Reserve about 1/2 cup of BBQ sauce for serving.
Cook on LOW setting for 7 hours. Remove the pork chops from the slow cooker and serve with additional BBQ sauce.